If the policies in your country allows you to do it, then you can give it a try. But I think it is pretty time consuming getting all required documents and licenses. Here there are some store-in-stores where an WU point there allows you to send or collect money. You can do the same with Bitcoin.
if there was a bitcoin transfer store it would do a lot of bitcoin thats for
sure. Making it much easier to buy and sell it.
Maybe some pawn shops will get involved with it soon like they do with gold and
silver