I made a post in another thread that is relevant to this one. I'll just make a partial quote here:
That is a very insightful thread, IMO, but Ripple itself is the counterparty for XRP, and they don't have any obligation to give you USD or other currency for it - they only have a vague promise that you can use it to process transactions in the future. It's as if I issued IOUs for backrubs for the rest of my lifetime, or if the postal service issued 1st class air mail stamps that are good for all eternity (actually the Norwegian postal service does this - which might get interesting in 100 years). 
XRPs are like the non-denominated 1st class stamps in Ripple. I like that analogy.
As an illustration, here's an example of these stamps. 

The Norwegian Postal Service sells one book of "A Verden" (first class air mail international) stamps for 150 NOK. But they will continue to honor them as long as they are in "business". Unlike traditional stamps which have are denominated in a currency like NOK, this is a bit like a Ripple XRP. 
Of course, unlike stamps, there are no "rare" or "special" XRPs - it's fungible and divisible. Also it's more likely that Ripple will collapse than that the Postal Service will collapse. They have some partial monopoly protections in some countries after all.
Edit:
Users will prefer XRPs as part of a trade over any IOUs
This remains to be seen. Bitcoiners prefer XRP over IOUs just like gold bugs would prefer platinum over dollars, but if Ripple is to become successful, it has to attract users who will use IOUs for transactions. To use the analogy above, the postal service can't be successful if the only ones it attracts is stamp collectors.
And even if the user Opencoin claims that XRP is a currency, I don't accept it as a real currency even if it has an acronym. It's more like stamps or frequent flier miles.