The topic moved around a bit, recently with a short excursion to Bitcoin privacy or it's lack of it. Coins are linked via transactions and those are public. If you can attribute coins or transactions to some person you can see a lot more than desired.
We can only obfuscate the links and make attribution a pain in the ass or a lot of guesswork.
I see an advantage of Bitcoin, compared to physical goods like physical money or gold or valuable stuff, because all coins are only "on the Bitcoin blockchain". You don't need to carry them with you. To cross borders with your Bitcoins, you "only" need to transport a way to access or reconstruct your wallet, your private keys which enable you to move your coins on the blockchain.
A lot of ways have been proposed how to hide and carry your wallet or key reconstruction details with you so that it's not obvious to spot. Whatever procedure you choose or prefer: keep it simple, keep it safe, don't shoot yourself in your feet.
I can't recall if it has been discussed if you can keep cool and not acting suspicious knowing what you hide when you cross borders. I guess there's no recipe and I have none, either. Would it help to spin the mantra "Keep calm, you're not doing anything wrong"?
You are absolutely right, psychological preparation is also very important in this situation. Yes, in my opinion, such psychological exercises as meditation or reading special mantras (psychological litanies) can help you. At the same time, such training should be done systematically.
You can also attend acting or improvisation courses. There are also board games, such as "Mafia". These games teach people to lie.
People are given cards with certain game roles - civilians, mafia, police commissioner, maniac, etc. The game time is divided into two parts - day and night. During the day, players can discuss among themselves, determining which of the players is the mafioso. By voting, one of the players is chosen for this role and is "executed" (he leaves the game). At night, the mafia "wakes up" and destroys one of the inhabitants of the world. As a result, at the end of the game, either the mafia or the civilians win.
To win this game, you need to be able to lie and not show your true emotions to strangers. Of course, such skills will help you pass customs at the airport without problems (if all other conditions are met).
Despite all the technical difficulties, in my opinion, Bitcoin provides the best way to move capital across international borders, from one country to another.