I agree with @BitMaxz.
PayPal is the riskiest method cause we can dispute the transaction, even though it is a very risky transaction option for some people still using the PayPal as option transaction. In case you are curious about the best practice for buying Bitcoin back then. Maybe this information could help.
New Liberty Standard created October 5, 2009.
How they work ?
Our exchange rate is calculated by dividing $1.00 by the average amount of electricity required to run a computer with high CPU for a year, 1331.5 kWh, multiplied by the the average residential cost of electricity in the United States for the previous year, $0.1136, divided by 12 months divided by the number of bitcoins generated by my computer over the past 30 days.
Source:
Do you know a first Bitcoin exchange? What is it, How it looks like?Now, we entering 2010 the years you're asking.
BitcoinMarket.com created March 17, 2010.
The first exchange for Bitcoin, and they got few payment option: Paypal, Liberty Reserve, Pecunix.
However, Paypal is being remove as the payment option since to many case with Paypal. These the reason:
The reasons were exactly those that had been predicted: fraudulent chargebacks had made the system unsustainable. Fraudsters had learned to exploit the mechanism systematically.
Source:
https://bitcoinmarket.net/magazine/bitcoinmarket-first-bitcoin-exchange-history-en.htmlMt. Gox Starting Trading July 2010
Same things like BitcoinMarket.com they got a problem as well with payment option Paypal. Liberty Reserve are mostly they're focused after issue fraud.
Direct P2P with Escrow in Bitcointalk
This things still being using back then, some Moderator Bitcointalk or Trusted person with a good trust in forum opened a escrow service.
Back to the topic question with the history back then. In 2010 July/August, people will using majority BitcoinMarket.com & Mt. Gox. Paypal are the most option payment is being avoided and people are mostly using Liberty Reserver since the payment transaction can't being rolled back and 100% irrevocable